Titanium Nitride-Supported Platinum with Metal–Support Interaction for Boosting Photocatalytic H<sub>2</sub> Evolution of Indium Sulfide
نویسندگان
چکیده
Metal–support interaction strongly influences the catalytic properties of metal-based catalysts. Here, titanium nitride (TiN) nanospheres are shown to be an outstanding support, for tuning electronic property platinum (Pt) nanoparticles and adjusting morphology indium sulfide (In2S3) active components, forming flower-like core–shell nanostructures (TiN-Pt@In2S3). The strong metal–support between Pt TiN through formation Pt–Ti bonds favors migration charge carriers leads easy reducibility TiN-Pt, thus improving photocatalytic atom efficiency Pt. TiN-Pt@In2S3 composite shows reduction loading by 70% compared optimal Pt-based system. In addition, exhibits a H2 evolution rate 4 times that reference. This increase outperforms all other supports reported far.
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ژورنال
عنوان ژورنال: ACS Applied Materials & Interfaces
سال: 2021
ISSN: ['1944-8244', '1944-8252']
DOI: https://doi.org/10.1021/acsami.0c20919